Efficiency of Photodegradation Properties of Nickel Calciate Nanoparticle Synthesized by solution combustion method

A.M. Santhosh¹ , K. Yogendra² , K.M. Mahadevan³ , I.H. Mallikarjuna⁴ , N. Madhusudhana⁵

Section:Research Paper, Product Type: Isroset-Journal
Vol.6 , Issue.5 , pp.48-56, Oct-2018

CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v6i5.4856

Online published on Oct 31, 2018

Copyright © A.M. Santhosh, K. Yogendra, K.M. Mahadevan, I.H. Mallikarjuna, N. Madhusudhana . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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Abstract :
In the present work, With the intention of removal of colour from Coomassie Brilliant Blue R (CBBR), a triphenylmethane azo dye using the synthesized Nickel Calciate nanoparticles (NiCaO2) in presence of natural sunlight. The nanoparticles were synthesized by using solution combustion method and characterisation was done by Scanning Electron Micrograph (SEM), X-Ray Diffraction (XRD), Energy Dispersive X-ray (EDX), Brunauer Emmett-Teller surface area determination and point zero charge determined by pH drift method. The band gap was determined by using UV-absorption spectroscopy. The rate of degradation efficiency was studied by varying different parameters such as catalyst concentration, solution pH dye concentration. The rate of degradation is highly efficient in 5Ă—10-4 mol/dm3 dye concentration with pH 6 and constant catalyst concentration 0.027g/50ml. Pseudo first-order rate constants and initial rates were determined and the photocatalytic mechanism was proposed. The result proves that NiCaO2 can be used for removal of dyes from CBBR.

Key-Words / Index Term :
Catalyst, Coomassie Brilliant Blue R, Nanoparticles, NiCaO2, Photodegradation

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