Volume-4 , Issue-4 , Aug 2017, ISSN 2455-3174 (Online) Go Back

• Open Access   Article

  Thermoacoustic Study of Electrolytic Solutions of Aloe Vera Juice at 303.15k

  M.S. Chouhan, R.S. Chouhan, B.R. Patil, K. Modi, B.D. Shrivastava, S.Patil

  Research Paper | Isroset-Journal (IJSRCS)

  Vol.4 , Issue.4 , pp.1-4, Aug-2017

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  Abstract
  Acoustical parameters such as adiabatic compressibility, acoustic impedance, intermolecular free length and bulk modulus have been estimated using standard relations from measured values of Ultrasonic velocities and densities in extensive range of concentrations at 303.15K temperature and 2MHz frequency for NaCl + Aloe vera juice and MgCl2 + Aloe vera juice system to study the ion-solvent interactions. During the investigation in non-aqueous solutions of electrolytes we have observed the interesting feature of a linear decrease of ultrasonic velocity with increase in concentration of NaCl and MgCl2 unruly to the normal type of behavior exhibited in general by electrolytes.

  Key-Words / Index Term
  Binary mixture, ion-solvent interactions, Aloe vera juice, Bulk modulus

  References
  [1] A Surjushe et al, “Aloe Vera: A short review”, Indian Journal of Dermatology, Vol.53, Issue.4, pp.163-166, 2008.
  [2] S Arunkumar et al, “Analysis of phytochemical constituents and antimicrobial activities of Aloe vera L. against clinical pathogens”, World. Journal of Agricultural Science, Vol.5, Issue.5, pp. 572-576, 2009.
  [3] P K Sahu, “Therapeutic and medicinal uses of Aloe vera: A review”, Journal of Pharmacology & Pharmacy, Vol.4,Issue.,pp. 599-610, Nov.2013.
  [4] K P Sampath kumar et al, “Aloe vera: A potential Herb and its Medicinal Importance”, Journal of Chemical and Pharmaceutical .Research, Vol.2, Issue.1, pp. 21-29,2010.
  [5] R S Chouhan, M S Chouhan et al, “Acoustic study of ethanolic binary mixture of natural sap of phoenix sylvestris at different temperature” Research Journal of Physical Science, Vol.5, Issue.2, pp. 1-4, 2017.
  [6] S Phadke, B D Shrivastava, A Mishra, “Acoustical parameter of aqueous solution of Borassus Flablifier Fruit pulp by non destructive method”, Journal of Trans Tech Publication, Defect and Diffusion Forum, Vol. 312, pp. 358-363, 2011.
  [7] V Kannappan, V S Chidambara, “Ultrasonic investigation of ion-solvent interactions in aqueous and non-aqueous solutions of transition and inner transition metal ions”, Indian Journal of Pure & Applied Physics, Vol. 45, pp. 143-150, 2007.
  [8] M S Chouhan , R S Chouhan et al, “Ultrasonic investigation of Aloe Vera juice, Water, ethanol, n-Butanol and acetic acid at 298K temperature and 2MHz frequency by NDT”, International Journal. of applied Research, Vol.2, Issue.8, pp. 301-304, 2016.
  [9] B R Shinde, K M Jadhav, “Ultrasonic investigations of molecular interactions in aqueous electrolytic solutions at varying temperatures”, Journal of engineering Research and Studies, vol. 1, Issue. 1, pp.128-137, 2010.
  [10] T Sumathi, M Varlakshmi, “Ultrasonic velocity, density and viscosity measurement of methionine in aqueous electrolytic solutions at 303K”, Rasayan Journal of Chemistry, Vol. 3 Issue.3, pp. 550-555, 2010.
  [11] S Mishra, R Paikaray, “Study of Molecular interaction and Association in binary mixture of DEHPA with n- Butyl chloride at different temperatures”, Journal of Acoustic Society of India, Vol.37, Issue.1, pp.20-24, (2010)
  [12] R Kumar, S Jaykumar, V Kannappan, “Study of molecular interactions in binary liquid mixture”, Indian Journal of pure& Applied Physics, Vol.46, pp. 169-175, 2008.
  [13] S Pravakar, L Rajagopal, “Study of molecular interactions in aprotic-aprotic binary mixtures through ultrasonic measurement”, Journal of Pure & Applied Ultrasonics, Vol. 27, pp.41- 48, 2005.
  [14] G Nithya, B Thanuja, “Study of intermolecular interactions in binary mixture of 2-chloro-4- methoxy-3nitro benzyl in various solvents and at different concentrations by the measurements of acoustic properties”, Ultrasonic Sono chemistry, Vol.20, pp.65-270, 2013.
  

  Citation
  M.S. Chouhan, R.S. Chouhan, B.R. Patil, K. Modi, B.D. Shrivastava, S.Patil, "Thermoacoustic Study of Electrolytic Solutions of Aloe Vera Juice at 303.15k," International Journal of Scientific Research in Chemical Sciences, Vol.4, Issue.4, pp.1-4, 2017

• Open Access   Article

  A Special Category of Electrolyte Prepared By Complexation of Zinc With Conducting Poly Aniline

  Anubha Vijay Pandya

  Research Paper | Isroset-Journal (IJSRCS)

  Vol.4 , Issue.4 , pp.5-7, Aug-2017

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  Abstract
  Complexes of Poly Aniline with Metal ions generally have versatile tendency in salt containing crystalline phase and soluble salts containing amorphous amorphous elastomeric phase exhibits conductivity of poly Aniline Polymeric material. Conducting Poly Aniline can be obtained by two methods 1) by electrochemical doping 2) Complexation with mono,di, trivalent metal ions. Due to great conducting environmental stability ,Poly Aniline is an important electroactive material. The chemical and electrochemically induced doping process greatly modifies the conducting properties of the polyaniline.Its conductivity on complexation is arousing considerable commercial interests. The Application of Poly Aniline and the related composite materials in polymer electronics is analyzed briefly.[1] The another category of includes those polymeric material that offer reversible electrochemical devices with unique characteristics of great importance in the presently developing technology. These days study and implementation of various types of conducting polymers have been carried out in India and all over the world. It is observed that conductivity of Poly Aniline can be modified by changing its method of synthesis. The Application of Poly Aniline and the related composite materials in polymer electronics is analyzed briefly.[1] The another category of includes those polymeric material that offer reversible electrochemical devices with unique characteristics of great importance in the presently developing technology. The Application of Poly Aniline and the related composite materials in polymer electronics is analyzed briefly.[1] The another category of includes those polymeric material that offer reversible electrochemical devices with unique characteristics of great importance in the presently developing technology.[1] The other type includes those polymers which offer reversible electrochemical devices with unique characteristics of great importance in the presently developing technology.

  Key-Words / Index Term
  Conducting Poly Aniline Polarography, half wave potential, diffusion current dropping mercury

  References
  [1]. Z. A. Boeva and V. G. Sergeyev, “Polyaniline: Synthesis, properties, and application,” Polymer Science Series C, vol. 56, no. 1, pp. 144–153, Jul. 2014.
  [2]. Youn Chaol on ,Park yong Woo. Hanguk Multi.Hakh-oechl,Ungyong Mulli, 2(3), 256- 60(Korean)(1989).
  [3]. C. Herold, R.Yazami, D.Billaud, Terre (France)
  [4]. W.John Albery, Zheng Chem., Benjamin R.Horrocks, Andrew R. Mount and Peter. J.Wilson, David Bloor Andew T. Monkmann, C.Michal Elliot, Fabradar Chem. Soc. 88, 247-259(1989)
  [5]. Bruno Scrosati, solid state ionic devices, 18-23 July 131-133(1988)
  [6]. Lingane JJ. Interpretation of the Polarographic Waves of Complex Metal Ions. Chemical Reviews. 1941 Aug;29(1):1-35.
  [7]. N. Gospodinova, D. A. Ivanov, D. V. Anokhin, I. Mihai, L. Vidal, S. Brun, J. Romanova, and A. Tadjer, “Unprecedented Route to Ordered Polyaniline: Direct Synthesis of Highly Crystalline Fibrillar Films with Strong π-π Stacking Alignment,” Macromolecular Rapid Communications, vol. 30, no. 1, pp. 29–33, Jan. 2009
  [8]. S. Jussila, M. Puustinen, T. Hassinen, J. Olkkonen, H. G. O. Sandberg, and K. Solehmainen, “Self-aligned patterning method of poly(aniline) for organic field-effect transistor gate electrode,” Organic Electronics, vol. 13, no. 8, pp. 1308–1314, Aug. 2012.
  

  Citation
  Anubha Vijay Pandya , "A Special Category of Electrolyte Prepared By Complexation of Zinc With Conducting Poly Aniline," International Journal of Scientific Research in Chemical Sciences, Vol.4, Issue.4, pp.5-7, 2017

• Open Access   Article

  Synthesis and effect of 7-{4-[ 2- Chloro- 4-N,N-di (2-hydroxyethyl) amino] phenylazo} phenyl- 6-oxo-2-methyl-4-(4-methoxy- 3-methylphenyl)- oxazolo [ 5,4-b ] pyridine On Polyester Fiber

  Anita Abhishek Singh Gour

  Research Paper | Isroset-Journal (IJSRCS)

  Vol.4 , Issue.4 , pp.8-11, Aug-2017

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  Abstract
  The demand for various dyes of high wet fast ness on polyester isincreasing Polyestes tends to have better fastness to wet treatments such as washing and perspiration fastness . all disperse dyes gave very good to excellent results. Azo dyes cover a whole gamut of colours, from yellow to brown hues, by varying theintermediates especially when heterocyclic diazo components are coupled to aminobenzene couplers substituted with powerful electron donating groups.

  Key-Words / Index Term
  Disperse azo dyes, Diazoniumsalt , XENO test, Thermo Test, Tinctorial Power

  References
  [1]. Straley, J. M., “ The Chemistry of Synthetic Dyes”, Vol. III, Academic press, New York, pp.1-385, 1962.
  [2]. H. S. Freeman and J. Sokolowska, “Developments in dyestuff chemistry from Book “Coloration Technology”, Willey, Englend, Vol.32, Issue.1, 1999.
  [3]. Inventors :Hihara Toshio , Hiroshi Inoue , WataruSeto, Japanese Patent Application , “Yellow disperse dye mixture which has a high level of light fastness”, US 7097670 B2 , Date of publication 29 Aug 2006, Rights holders First Named : DystarTextilfarbenGmbh& Co. Deutschland Kg
  [4]. D. M. Lewis and P. J. Broadbent, “A Universal Dye for All Fibres - Are Disperse Dyes Capable of Fulfilling this Vision”, J. Soc. Dyers Colour., 118, 151(1997).
  [5]. Arthur I. Vogel “A Text-Book of Practical Organic Chemistry”, 5th Ed. Longman Scietific and Technical, Englend, Pg. 1010
  [6]. Lecher “The Chemistry of Synthetic Dyes and Pigments”, Journal of the American Chemical Society, Vol.77, Issue.22, pp.6075-6076, 1995.
  

  Citation
  Anita Abhishek Singh Gour , "Synthesis and effect of 7-{4-[ 2- Chloro- 4-N,N-di (2-hydroxyethyl) amino] phenylazo} phenyl- 6-oxo-2-methyl-4-(4-methoxy- 3-methylphenyl)- oxazolo [ 5,4-b ] pyridine On Polyester Fiber," International Journal of Scientific Research in Chemical Sciences, Vol.4, Issue.4, pp.8-11, 2017