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• Open Access   Article

  Behaviour of Sodium-2 Hydroxy Benzoic Acid in the Ternary Mixture with Water and Ethanol- An Ultrasonic Study

  PJ. Ganjare, SS. Aswale, SR. Aswale

  Research Paper | Isroset-Journal (IJSRCS)

  Vol.4 , Issue.2 , pp.1-6, Apr-2017

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  Abstract
  Present paper, discusses about the measurement of ultrasonic speed, density and viscosity of sodium salicylate solution using ethanol and water in 1:1 ratio as a solvent at 298K, 303K, and 308K and ultrasonic speed at 4MHz frequency. By using these experimental values, various thermodynamic as well as acoustic parameters have been calculated. It is found that the value of these parameters have close relationship with the molecular interactions in the solutions. The data shows that the molecular interaction exists in ternary mixtures and also there is a strong solute–solvent interaction occurring in ternary solutions. This indicates that there may be hydrogen bonding between –COOH group of 2-hydroxy benzoic acid, ethanol and molecules of water.

  Key-Words / Index Term
  Ultrasonic Velocity, Relaxation Time, Acoustic Impedance, Wada׳S Constant

  References
  [1] K. Raju , K. Karpagavali, P. Krushnamurthy, “Ultrasonic studies of molecular interactions in the solutions of poly(propylene glycol) 400 in N-alkanols”., Euro.J.appl.eng.sci.res,Vol.1, No.4, pp.216-219, 2012.
  [2] S. Baluja, P. Ramavat., “Study of molecular interactions in solutions of phenyl pyrimidine derivatives in 1,4 dioxane at 298.15K”, International Journal of Technical Research and Applications, Special Issue 12, PP. 59-62, 2015.
  [3] S.L. Oswal , H.S. Desai, “Studies of viscosity and excess molar volume of binary mixtures 1-alkanol+ di –n-propylamine and di-n-butyl amine mixtures at 303.15 and 313.15K”, Fluid phase equilibria., Vol. 186, pp.81-102, 2001.
  [4] Palani R. ,Saravanan S. and . Kumar R, “Ultrasonic studies on some ternery organic liquid mixtures at 303K,308K and 313K”, Rasayan J.Chem, Vol.2, No.3, 622-629, 2009.
  [5] S.S. Aswale, S.R. Aswale, R.A. Hajare, “Ultrasonic Investigation of Molecular Interaction in Paracetamol Solution at Different Concentrations”, J. Chem. Pharm. Res., Vol.4, pp. 2671– 2677, 2012.
  [6] S.S. Aswale, S.R. Aswale, R.S. Hajare, “Adiabatic compressibility, intermolecular free length and acoustic relaxation time of aqueous antibiotic cefotaxime sodium”, J. Chem. Pharm. Res., , Vol.4(5), pp.2671-2677, 2012.
  [7] V.K. Syal, R. Gautam, R. Chauhan, “Ultrasonic measurements of sucrose in binary solvent mixtures of water+acetonitrile at 25,35,and 450C,” Ind. J. Pure Appl. Phys, Vol.36, pp.108-112, 1998.
  [8] J.V. Srinivasu, K. Narendra, B. SubbaRao, “Refractive Properties of Binary Mixtures of 1,4-Butanediol with Methylpyridine Isomers”, Int. J. Sci. Res. in Chemical Sciences Vol-3(1), pp.1-12, 2016.
  [9] A.N. Kannapan, R. Kesavsamy, V. Ponuswamy, “Molecular studies in the ternery liquid mixtures of pyrimidine + benzene + N, N, dimethylformamide by ultrasonic velocity measurements”, ARPN Journal of Eng. and appl. sciences. Vol.3, No.4 pp.41-45, 2008.
  [10] DS Kumar, D.K. Rao, “Study of molecular interactions and ultrasonic velocity in mixtures of some alkanol with aqueous propylene glycol”, Indian journal of pure and applied physics., Vol.45, No.3, pp.210-220, 2007.
  [11] K. Kaur, K.C. Juglan, “Studies of molecular interaction in the binary mixture of chloroform and methanol by using ultrasonic technique”, Scholars Research Library Der Pharma Chemica, Vol.7, No.2, pp.160-167, 2015.
  [12] SK.Md. Nayeem, M. Kondaiah, K. Sreekanth, D. Krishna Rao, “Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Cyclohexanone with Isomers of Butanol”, Journal of Applied Chemistr, Vol.2014, pp.1-11, 2014.
  [13] H. Eyring, J.F. Kincaid, “Free volumes and free angle ratio of molecules in liquids” J. Chem. Physics, Vol.6, pp.614-620, 1938.
  [14] M. Vigneswari, S. Kumar, V. Sureshbabu, N. Sankarrajan, “Molecular interactions in solutions of polyvinyl alcohol:an ultrasonic study”, Int. J. of Ad. Che.y, Vol.4, Issue.2, pp.1521, 2016.
  [15] S. Thirumaran, K. Indhu, “Ultrasonic studies in ternery mixtures of substituted benzenes in toluene with pyridine at different temperatures”, Rasayan J. Chem, Vol.2, No.3, pp.760-768, 2009.
  [16] A. Ali, A.K. Nain, “Ultrasonic investigation of ion-solvent interactions of sodium chloride in aqueous dimethyl formamide mixtures”, J.Pure and appl.Ultrason., Vol.16, pp.74-77, 1994.
  [17] Dash Ashok Kumar and Paikaray Rita, “Ultrasonic Study on Ternary Mixture of Dimethyl Acetamide (DMAC) in Diethyl ether and Acetone”, Research Journal of Physical Sciences, Vol.1, No.3, pp.12-20, 2013.
  

  Citation
  PJ. Ganjare, SS. Aswale, SR. Aswale, "Behaviour of Sodium-2 Hydroxy Benzoic Acid in the Ternary Mixture with Water and Ethanol- An Ultrasonic Study," International Journal of Scientific Research in Chemical Sciences, Vol.4, Issue.2, pp.1-6, 2017

• Open Access   Article

  Synthesis and effect of Actamido Phenyl Azo 2-6 Pyridinedione Based Dye on Polyester Fiber

  A. Gour

  Research Paper | Isroset-Journal (IJSRCS)

  Vol.4 , Issue.2 , pp.8-10, Apr-2017

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  Abstract
  In order to prepare a unique hue in disperse azo dyes synthesized by the coupling component of diazonium salt 1-[4-(2-Acetamido-4-N,N-diethylamino) phenylazo] phenyl-4-(4-methoxy-3-methylphenyl)-2,6-(1H,5H)-pyridinedione to produce the corresponding different azo disperse dyes (A- E). These dyes were consumed to polyester fabric and its effect was evaluated.

  Key-Words / Index Term
  Disperse azo dyes, Diazonium salt , XENO test, Thermo Test, Tinctorial Power

  References
  [1]. MF. Comelo “Coloration Technology”, Willey, Vol.32, Issue.1, pp.1–12, 2002
  [2]. J. Shore, “Blends Dyeing”, SDC, Bradford, pp.10–19, 1998.
  [3]. HS. Freeman, J. Sokolowska, “Developments in dyestuff chemistry from Book “Coloration Technology, Vol.29, Issie.1, pp.8-22, 1999.
  [4]. H Toshio , H Inoue , W Seto, “Yellow disperse dye mixture which has a high level of light fastness”, Dystar Textilfarben Gmbh & Co Deutschland Kg, UA, pp.1-29, 2006.
  [5]. DM. Lewis, PJ. Broadbent, “A universal dye for all fibres - are disperse dyes capable of fulfilling this vision?”, Journal of the Society of Dyers and Colourists, Vol.113, Issue.5, pp.159-64,1997.
  [6]. AI. Vogel, “A Text-Book of Practical Organic Chemistry”, Longman Scietific and Technical, Englend, pp.1-1000, 1948.
  [7]. J. W. COOK, "A Text-Book of Practical Organic Chemistry", Nature, Vol.161, pp.995-995, 1948.
  [8]. Lecher, “The Chemistry of Synthetic Dyes and Pigments”. Journal of the American Chemical Society, Vol.77, Issue.22, pp.6089-6089, 1995.
  [9]. D. W. Rangnekar, P.Y. Kamath, “synthesis of 3-amino-2-arylazo-4,6 dimethyl thieno[2,3]pyridines and their application on polyester fibres as disperse dyes”, Indian Journal of Fiber and Textile Research,Vol.17 pp.98-100, 1992.
  

  Citation
  A. Gour, "Synthesis and effect of Actamido Phenyl Azo 2-6 Pyridinedione Based Dye on Polyester Fiber," International Journal of Scientific Research in Chemical Sciences, Vol.4, Issue.2, pp.8-10, 2017